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Extra info for Advances in Chemical Propulsion (auth unkn) [No TOC]
Kailasanath. Washington, DC: Naval Research Laboratory. 130–38. 13. Marchand, A. , A. Zope, F. Zaragoza, H. L. Ammon, and Z. Du. 1994. Synthesis, characterization and crystal density modeling of four C24 H28 cage-functionalized alkenes. Tetrahedron 50:1687–98. 14. Marchand, A. , D. Vidyanand, Z. Liu, K. A. Kumar, F. Zaragoza, L. K. Talafuse, S. G. Bott, W. H. Watson, R. P. Kashyap, and H. L. Ammon. 1996. Synthesis, characterization and crystal density modeling of polycarbocyclic oxiranes. Tetrahedron 52:9703–12.
9 eV, and it was found that the ability to distinguish quadricyclane from norbornadiene is lost for energies above ∼ 5 eV, where conventional tandem mass spectrometers operate. As expected from this result, previous mass spectral studies of C7 H8 have been unable to distinguish quadricyclane and norbornadiene [18–22]. 5 Extraction of Breakdown Curves The data just described provide considerable insight into the thermal breakdown behavior of the strained molecules of interest, yielding both product species distributions and stability information.
010,14 ]tetradecane-7-one (HCTD-7-one, 18) and 1-(4 -pyridyl)-HCTD (24) in low isolated yield (Scheme 7) . 010,14 ]tetradecane-10-one (27), both of which resulted via oxidative cleavage of the C(1)–C(2) σ-bond in 22 (see Scheme 8) . 5 Synthesis of a Novel, Polycarbocyclic Alkene which Contains a Strained, Planar C=C Double Bond  The availability of 18 in one synthetic step via direct oxidative functionalization of HCTD [19–21] allows exploration of this valuable compound’s chemistry, for the ﬁrst time.
Advances in Chemical Propulsion (auth unkn) [No TOC]